On Saturday, Morawiecki vowed to do everything possible to limit the environmental devastation. Poland's interior minister said a reward of 1 million zlotys ($220,000) would be paid to anyone who helps track down those responsible for polluting the river.
Authorities in the northeastern German state of Mecklenburg-Western Pomerania warned people not to fish or use water from the Szczecin lagoon, as the river's contaminated water was expected to reach the estuary area on Saturday evening.
"The extent of the fish die-off is shocking. This is a blow to the Oder as a waterway of great ecological value, from which it will presumably not recover for a long time," said Alex Vogel, the environment minister for Germany's Brandenburg state, along which the river runs.
The head of Polish waters, Poland's national water management authority, said Thursday that 10 tons of dead fish had been removed from the river. Hundreds of volunteers were working to help collect dead fish along the German side.
German laboratories said they detected "atypical" levels of "salts" that could be linked to the die-off but wouldn't fully explain them on their own.
Morawiecki acknowledged that some Polish officials were "sluggish" in reacting after huge numbers of dead fish were seen floating and washing ashore, and said two of them were dismissed.