Botanist Marta Pereira, who is delighted to have secured his services, says there are only about 20 people who can do what he does.
"For us, they're vital... without them we wouldn't have any samples," said Pereira, a researcher at the Amazon state university.
These tree climbers are even more important in an area where scientists believe they know only about 30 percent of the biodiversity.
Dressed in just a T-shirt and Bermuda shorts, Zelao climbs five or six times a day up trees that can reach 50 meters (some 164 feet) in height.
He collects fruit, leaves or cuts branches.
For security he has a harness, a rope and thick rubber-soled boots. Sometimes he clambers from one tree to another.
"It is very risky and requires a lot of technique, a lot of physical preparation," said Zelao, adding that he has already undergone surgery four times on damaged ligaments.
Even so, he has no intention of slowing down.
"It's very difficult to find a climber. My schedule is booked until December 20," he said.